My research activities, since 1988, focus on the crystal chemistry of Li+, Ag+ or Na+-containing solid state electrolyte ceramics and on Li+/ Na+ intercalation compounds to be used as positive electrodes in rechargeable batteries.
We try to address complex phenomena and properties of ionic conduction, non-stoichiometry, phase transitions, electrochemical insertion/extraction within several structural families of materials, oxides, phosphates, silicates, borates, ..., of transition metal elements.
Numerous crystal structure determination studies are conducted by means of X-Ray and Neutron diffraction, on polycristalline powders and single crystals, so as to correlate these crystal structures with the observed properties. Among significant structural determinations of NEW materials or NEW forms of already known materials are :
Na7Fe3(P2O7)4 : big superstructure due to Na-Vacancy ordering in a 2-D ion conductor
(papers #1 (1990), #2 (1991), #5 (1994) with F. d'YVOIRE and G. COLLIN)
Na7Fe4(AsO4)6 : 1 Fe2+ / 3 Fe3+ charge ordering within a Fe4O18 Cluster
(paper #10 (1995) with F. d'YVOIRE and G. COLLIN)
Li3Fe2(PO4)3 : the NASICON - analogue was prepared for the first time by ion exchange from Na3Fe2(PO4)3. A new crystallographic site, Li(3), was spoted for Lithium (space group R-3)
(papers #16 (1997), #17 (1997), #22 (1998), #32 (2000) with J. B. GOODENOUGH, J. RODRIGUEZ-CARVAJAL, A.K. PADHI, J. GAUBICHER, L.F. NAZAR)
LiMn2O4 : discovery of charge ordering for the stoichiometric composition, below RT, in a 3x3 orthorhombic supercell (space group Fddd)
(papers with G. ROUSSE, J. RODRIGUEZ-CARVAJAL, M. HERVIEU)
LiFePO4 and FePO4 : magnetic structures published for the first time. Interesting phenomena of super super exchange interactions in isostructural frameworks
(papers with G. ROUSSE and J. RODRIGUEZ-CARVAJAL
VP2O7: a new V4+ - containing di-phosphate, obtained by chemical or electrochemical extraction of Li+ from LiVP2O7
(papers with C. WURM anf G. ROUSSE
Li2FeSiO4 : A new form of Li2FeSiO4, obtained by quenching at 700°C, was determined for the first time, in space group P21/n
(papers with C. SIRISOPANAPORN, R. DOMINKO, P.G. BRUCE
Na3Ti2(PO4)3 : big superstructure due to Na/vacancy ordering at low temperature, for this Ti3+-containing NASICON-based material.
(papers with H. KABOUR, O. MENTRE, G. ROUSSE
(papers with S. HAMELET, M. CASAS-CABANAS,
(papers with Y. DENG and S.ISLAM
(papers with M. BIANCHINI, L. CROGUENNEC, F. FAUTH
(papers with E. BOIVIN, L. CROGUENNEC, J.N. CHOTARD,
(papers with L.F. NAZAR, G. ROUSSE, J.N. CHOTARD,
(papers with M. BIANCHINI, L. CROGUENNEC, F. FAUTH,
(papers with M. BIANCHINI, L. NGUYEN,
Na3PS4 : A new polymorph, named "gamma" was discovered to crystallize as a "plastic crystal" above 500°C with super fast Na+ ion transport properties.
(papers with T. FAMPRIKIS, J. DAWSON, S. ISLAM, F. FAUTH, E. SUARD, J.N. CHOTARD,
Please have a glance at this paper to get a flavour of what we love to do !! Chem Rev
This research has been conducted mainly within four laboratories (ICMMO Orsay, AIST Osaka, UT Austin, LRCS Amiens) together with many PhD students, Post-docs and colleagues from all over the world, greatfully acknowledged here.
December 29, 2021 : Paper on the structure of Na2V2(PO4)3, solved by Sunkyu PARK, published in Chem. Mater.
December 17, 2021 : Cédric BARCHA is now a "Docteur de l'Université de Picardie Jules Verne", Amiens, FRANCE. For his great work on interface stabilities in solid state batteries, in collaboration with RENAULT through a CIFRE funding.
December 14, 2021 : Kickoff of the DESTINY PhD Cofund Marie Curie Project (50 PhDs....) in Amiens as a joint event with the ALISTORE bi-annual Meeting
December 2, 2021 : Na2V2(PO4)3 spotted by Ziliang WANG and P. CANEPA'S team (NUS Singapore) through computational methods, published in J. Mater. Chem. A
June 19, 2021 : One more great paper from Theodosios FAMPRIKIS on Na3PS4, accepted in Chem. Mater.
June 15, 2021 : First paper from Sunkyu PARK on his PhD work, on NaxFeV(PO4)3, accepted in Chem. Mater.
March 29 & 30, 2021: Oral interviews for the Marie Curie PhD CO-FUND project DESTINY. 29 topics on "batteries" in Europe.
November 10, 2020: Theodosios FAMPRIKIS is now a "Docteur de l'Université de Picardie Jules Verne", Amiens, FRANCE. For his great work on solid electrolytes, in particular Na3PS4, in collaboration with Prof. S. ISLAM @ Univ. Bath, through an ALISTORE funding.
September 24, 2020 : Paper accepted in J. Mater. Chem. A on Na7V3(P2O7)4, with Vadim KOVRUGIN as main author.
September 14, 2020 : Paper accepted in J. Amer. Chem. Soc. on Na3PS4 and pressure effects on solid electrolytes, with Theodiosios FAMPRIKIS as main author.
August 30, 2020 : Paper accepted in J. Power Sources, a review on Na-Batteries, with Montse CASAS-CABANAS as leader of a great team of contributors.
July 13, 2020 : 30 PhD topics received for the first Pre-Call of the MSCA PhD Cofund project DESTINY. An exciting adventure begins.
June 8, 2020 : Paper accepted in J. Power Sources on Na-containing Antiperovskites, with Ernest AHIAVI and Theo FAMPRIKIS as main contributors.
May 29, 2020 : Omer Ulas KUDU is now a "Docteur de L'Université de Picardie Jules Verne", Amiens, FRANCE. For his great work on solid electrolytes within the Li2S-P2S5 system, in collaboration with SOLVAY.
April 1, 2020 : Official start of our Bilateral ANR-NSG, i.e. France-Singapore, project on Na-containing solid electrolytes, with Pieremanuele CANEPA, Stefan ADAMS and Tony CHEETHAM as collaborators from NUS, Jean-Noël CHOTARD, Vincent SEZNEC and Christine FRAYRET as co-workers from LRCS.
February 3, 2020 : The EU informs me that they accepted our 8 Million Euros Marie Curie COFUND project, DESTINY. 50 PhD projects to be granted to talented students witin the frames of the ALISTORE Network and the BATTERY 2030+ Initiative.
February 6 & 7, 2020 : The National Committee on Materials Science (CNU, Section 33) gathers in Montpellier to examine the files of candidates for "Qualifications" for Assistant-Professor and Full Professor positions in France.
January 8, 2020 : Congrats to Theodosios FAMPRIKIS, recipient of the Ludo Frevel Crystallography Scholarship Award from ICDD.
December 12, 2019 : Long NGUYEN defended his PhD Thesis in Université de Bordeaux, FRANCE. Wonderful work. He will join Prof. Shirley MENG's group in UCSD, as a PDRA, starting March 2010.
December 10-11, 2019 : The 27th ALISTORE ERI Meeting was held in Barcelona, hosted by M.R. PALACIN. A special tribute to the Nobel Prize in Chemistry was given by Mike THACKERAY.
November 21, 2019 : Mathieu MORCRETTE, the head of LRCS, receives the "Médaille de Cristal" of the CNRS, a prestigious recognition for his achievements in Amiens
October 30, 2019 : The Crystal structure of a new polymorph of Na3PS4, discovered by Theo FAMPRIKIS, is published in ACS Materials Letters.
October 15-17, 2019 : Around 120 people gather in Amiens for the RS2E Meeting. Lots of excellent science on many fronts of advanced battery and supercapacitor research.
Sept. 26, 2019 : Submission of the DESTINY project under the Marie Curie COFUND Scheme : 40 partners from 12 countries, 50 PhD thesis to be funded.... Results in February 2020 !!
June 19-20, 2019 : 28th Meeting of the ALISTORE-ERI in Vitoria (SPAIN) in the premises of our Partner CIC-Energigune
March 25-27, 2019 : Meeting of the MESC+ Consortium in Toulouse, FRANCE, to select 20 students for EMJMD Scholarships, among many applicants (>250).
March 19-20, 2019 : Bi-annual Meeting of the RS2E Network, Lille, FRANCE.
March 4-8, 2019 : IBA International Meeting in UCSD, La Jolla, USA. Organized by Prof. Shirley MENG
October 17-18, 2018 : RS2E bi-annual Meeting (120 participants) in ICG Montpellier
October 1st, 2018 : Ulas KUDU's review paper on Li2S-P2S5 Solid Electrolytes accepted in J. Power Sources
September 27th, 2018 : Big proposal submitted for the Marie Curie COFUND action; DESTINY gathers 40 european partners for 53 PhD thesis proposed.
July 26th, 2018 : Fan CHEN's first paper accepted in SMALL Methods, on Na4MnV(PO4)3
July 24th, 2018 : Thibaut BROUX's paper accepted in SMALL Methods, on high rate Na3V2(PO4)2F3
June 26th, 2018 : MESC+ is granted as an EMJMD ERASMUS MUNDUS Master Course for 5 more years, with partners in Spain, Slovenia, Poland, France, USA and Australia
April 25th, 2018: Attending the 34th PSI Electrochemical Symposium in Villigen, SWITZERLAND. Talk on operando investigations of Li and Na battery materials.
April 24th 2018: Mattéo BIANCHINI's paper accepted in J. Mater Chem. A. on Na+ - Ag+ ion exchange in Na3V2(PO4)2F3
Jan. 19th, 2018: Simon MALIFARGE defends his PhD Thesis in UPJV Amiens
Dec. 12th, 2017: ALISTORE Meeting in Amiens, FRANCE. New Direction elected with P. JOHANSSON, R. DOMINKO and myself as Directors. Thanks A LOT to R. PALACIN and P. SIMON for their leadership during the previous term.
Dec. 11th, 2017: Thibault BROUX's paper accepted in Chem. Mater. on transpot properties of Na3V2(PO4)2F3
Nov. 29th, 2017: Attending the 4th International Na-ion Battery Conference in Tokyo, JAPAN.
Nov. 24th, 2017: Edouard BOIVIN defends hs PhD thesis in UPJV Amiens
Sept. 28th, 2017: Application for a COFUND Programme (Marie Curie Action)
May 30th, 2017: Attending the 8th ICE Conference in Nagoya, JAPAN
February 15th, 2017: New Application of MESC Consortium for ERASMUS + EMJMD.
February 5th, 2017: the LRCS moves to its new building, the HUB of the RS2E French Network on Electrochemical Energy Storage.
February 5th, 2017: Paper #2 of Thibault BROUX, on VIV disproportionation in NVPF upon charge, accepted in ACS J. Phys. Chem. C
February 1st, 2017: Paper #2 of Yue DENG, on mixed anion effect in solid electrolytes, accepted in ACS Applied Materials & Interfaces
October 24th, 2016 : Paper #2 of Edouard BOIVIN, on LiVPO4(F,O) accepted in J. Phys. Chem. C.
October 6th, 2016 : Paper #1 of Thibault BROUX on Na3V2(PO4)2F3 accepted in Chem. Mater.
October 5th, 2016 : The Nobel Prize for Chesmistry is attributed to Jean-Pierre SAUVAGE from Strasbourg.
June 28-29, 2016 : ERAMUS + Meeting in Brussels on "Mastering Joint Excellence under ERASMUS MUNDUS"
June 14-18, 2016 : IMLB 2016 in Chicago, 1800 attendees......
April 12-15, 2016 : Proposals Subcommittees and Scientific Council at ILL, Grenoble, FRANCE
March. 22, 2016 : Talk at IBA Conference, Nantes, France
Feb. 18, 2016 : Application of M.E.S.C. for ERASMUS + re-accreditation ......
Dec. 5, 2015 : Interview of Mathieu MORCRETTE, Director of LRCS, in "Agir en Picardie".
Nov. 23-25, 2015 :CNRS-sponsored ANF Chimie du Solide, organized in Caen, France.
Nov. 9, 2015 : PhD Defense of Fabien LALERE in UPJV Amiens
Oct. 23, 2015 : PhD Defense of Matteo BIANCHINI in UPJV Amiens
Sept. 15, 2015 : Graduation Ceremony in Amiens of Class#10 of M.E.S.C. Master Course.
Sept. 2, 2015 : invited Talk at European Conference on Neutron Scattering, Zaragoza, Spain
August 7, 2015 : New Crystal Structure of Na3V2(PO4)3 published in Chem. Mater.
July 1, 2015 : Yue DENG's first paper on Li4SiO4-Li3PO4 is published in JACS.
July 1, 2015 : Invited talk at ICMAT Singapore on highly defective LiFePO4 powders.
June 16, 2015 : Fabien LALERE gives a talk in SSI Conference, Keyston, USA
June 4, 2015 : Matteo BIANCHINI is the ECS Battery Student Award winner for 2015
June 1, 2015 : Robin AMISSE's paper on highly defective LiFePO4 accepted in Chemistry of Materials
Nov 24, 2014 : the www site
http://www.docteurs-chimie.fr/ is launched. There is in particular a very convenient Job section.
July 23, 2014 : Visit the www site of Nature related to CRYSTALLOGRAPHY, MILESTONES
July 11, 2014 : HDR Defense of Joël GAUBICHER, IMN Nantes, France
June 15-18 : EPDIC Conference in Aarhus, Denmark.
June 7-12, 2014 : IMLB conference, Como, Italy
May 6, 2014 : Comité de Sélection, Poste 33MCF0269, Amiens
April 16th, 2014 : Conseil Académique à l'UPJV Amiens.
April 2-4, 2014 : Power our Future at CIC Energigune, SPAIN
March 18 & 19, 2014 : ILL Subcommittees for experiments, Grenoble, FRANCE
March 3-7, 2014 : IBA Meeting in Brisbane, Australia
Feb. 24-25, 2014 : Meeting of the French RS2E in Lyon, FRANCE.
Feb. 11-13, 2014 : Meeting of the MESC Consortium in Marseille for the Selection of CLass#11 (2014-2016)
February 7, 2014 : All Solid State Battery Meeting of the RS2E.
February 7, 2014 : Na-ion Group Meeting of the RS2E
January 24, 2014 : Li-Ion Group Meeting of the RS2E in Collège de France, Paris
January 23, 2014 : Prof. J.M. TARASCON gives his Inaugural Lecture at College de France, Paris